TITLE 8: AGRICULTURE AND ANIMALS
CHAPTER I: DEPARTMENT OF AGRICULTURE
SUBCHAPTER i: PESTICIDE CONTROL
PART 259 AGRICHEMICAL FACILITY RESPONSE ACTION PROGRAM
SECTION 259.APPENDIX D GROUNDWATER CLEANUP OBJECTIVES (GWOBJ)



Section 259.APPENDIX D   Groundwater Cleanup Objectives (GWobj)

 

Name

 

CAS No.a

 

Recommended

Test  Methodb

 

Subsurface

(mg/L)c

 

Surface

(mg/L)d

 

 

 

 

 

 

 

 

 

acetochlor

 

34256-82-1

 

505

 

0.002j

 

0.01g

acifluorfen sodium

 

62476-59-9

 

515.1

 

0.091f

 

0.455g

alachlor

 

15972-60-8

 

505

 

0.002

 

0.01

aldicarb

 

116-06-3

 

531.1

 

0.003

 

0.015

aldrin

 

309-00-2

 

508

 

0.000005e

 

0.000025e

ammonia

 

7664-41-7

 

350.2

 

10.0o

 

50.0o

atrazine

 

1912-24-9

 

505

 

0.003

 

0.015

bentazon sodium

 

50723-80-3

 

515.1

 

0.21f

 

1.05g

bromacil

 

314-40-9

 

507

 

0.7f

 

3.5g

bromoxynil(o)

 

1689-99-2

 

 

 

0.14f

 

0.7g

butylate

 

2008-41-5

 

507

 

0.35f

 

1.75g

carbofuran

 

1563-66-2

 

531.1

 

0.04

 

0.2

chlordane

 

57-74-9

 

508

 

0.002

 

0.01

chlorimuron-ethyl

 

90982-32-4

 

 

 

0.14f

 

0.7g

chlorpyrifos

 

2921-88-2

 

525.2

 

0.021f

 

0.105g

cyanazine

 

21725-46-2

 

508.1

 

0.014l

 

0.07g

2,4-D

 

94-75-7

 

515.1

 

0.07

 

0.35

4,4'-DDD

 

72-54-8

 

508

 

0.0004e

 

0.002e

4,4'-DDE

 

72-55-9

 

508

 

0.0003e

 

0.0015e

4,4'-DDT

 

50-29-3

 

508

 

0.0003e

 

0.0015e

diazinon

 

333-41-5

 

507

 

0.00063l

 

0.00315g

dicamba

 

1918-00-9

 

515.1

 

0.21f

 

1.05g

dieldrin

 

60-57-1

 

508

 

0.000005e

 

0.000025e

dimethoate

 

60-51-5

 

8141h

 

0.0014f

 

0.007g

dinoseb

 

88-85-7

 

515.1

 

0.007

 

0.07

disulfoton

 

298-04-4

 

507

 

0.00028f

 

0.0014g

endosulfan

 

115-29-7

 

508

 

0.2e

 

1.0e

endothall

 

145-73-3

 

548.1

 

0.1

 

0.1

endrin

 

72-20-8

 

508

 

0.002

 

0.01

EPTC

 

759-94-4

 

507

 

0.175f

 

0.875g

glyphosate

 

1071-83-6

 

 

 

0.7k

 

3.5g

HCH-alpha

 

319-84-6

 

508

 

0.00001e

 

0.00005e

heptachlor

 

76-44-8

 

505

 

0.0004

 

0.002

heptachlor epoxide

 

1024-57-3

 

505

 

0.0002

 

0.001

lindane

 

58-89-9

 

508

 

0.0002

 

0.001

linuron

 

330-55-2

 

508

 

0.014f

 

0.07g

malathion

 

121-75-5

 

 

 

0.14f

 

0.7g

methoxychlor

 

72-43-5

 

508

 

0.04

 

0.2

metolachlor

 

51218-45-2

 

507

 

1.05f

 

5.25g

metribuzin

 

21087-64-9

 

507

 

0.175m

 

0.875g

nitrate, as N

 

7631-99-4

 

300.0

 

10.0c

 

100.0d

parathion, ethyl

 

56-38-2

 

8141h

 

0.042f

 

0.21g

parathion, methyl

 

298-00-0

 

8141h

 

0.00175f

 

0.00875g

pendimethalin

 

40487-42-1

 

 

 

0.28f

 

1.4g

permethrin

 

52645-53-1

 

 

 

0.35f

 

1.75g

phorate

 

298-02-2

 

8141h

 

0.0014i

 

0.007g

simazine

 

122-34-9

 

505

 

0.004

 

0.04

2,4,5-TP

 

93-72-1

 

515.1

 

0.05

 

0.25

terbufos

 

13071-79-9

 

507

 

0.00175i

 

0.00875g

toxaphene

 

8001-35-2

 

508

 

0.003

 

0.015

trifluralin

 

1582-09-8

 

508

 

0.0525f

 

0.2625g

 

Notes:

a      Chemical Abstract Service (CAS)

b      USEPA "Methods for the Determination of Organic Compounds in Drinking Water" Supplement III of 1995

c      Groundwater Quality Standards for Class I: Potable Resource Groundwater (35 Ill. Adm. Code 620.410)

d      Groundwater Quality Standards for Class II: General Resource Groundwater (35 Ill. Adm. Code 620.420)

e      Tiered Approach to Corrective Action Objectives (TACO): Values Used to Calculate the Tier I Soil Remediation Objectives for the Migration  to Groundwater Portion of the Groundwater Ingestion Route (35 Ill. Adm. Code  742.Appendix B:Table F)

f       Human Threshold Toxicant Advisory Concentration (HTTAC) from "Procedures for Determining Human Threshold Toxicant Advisory Concentration for Class I: Potable Resource Groundwater" (35 Ill. Adm. Code 620.Appendix A) using values from Integrated Risk Information System (IRIS), USEPA

g      Class II GWobj values based on Class I GWobj values times 5

h      USEPA "Test Methods for Evaluating Solid Wastes, Physical/Chemical Methods (SW-846)", July 1992

i       HTTAC using values from Health Effects Assessment Summary Tables (HEAST), 1997, USEPA

j       Value from the Acetochlor Registration Agreement monitoring program, http://www.epa.gov/oppefed1/aceto/index.htm

k      MCL value from Drinking Water Standards and Health Advisories (Summer 2000, EPA 822-B-00-001)

l       HTTAC using RfD value from Drinking Water Standards and Health Advisories (Summer 2000, EPA 822-B-00-001)

m     HTTAC using RfD value from Risk Assessment Information System (RAIS), http://risk.lsd.ornl.gov/rap_hp.shtml

n      In order to provide environmentally conservative default SCOs that take into account the potential for long-term nitrification, one-third of the USEPA's Lifetime Health Advisory Level for ammonia in drinking water (30 mg/L) is used as basis for the groundwater cleanup objectives for Class I and Class II groundwater (U.S. Environmental Protection Agency, 2004, 2004 Edition of the Drinking Water Standards and Health Advisories, Office of Water, Washington, D.C., EPA 822-R-04-005).  Although the Lifetime Health Advisory Level was established for ammonia, most of the dissolved ammonia occurs as ammonium within the pH range (5.6-9.0) of Illinois groundwater.

 

(Source:  Amended at 32 Ill. Reg. 1308, effective January 21, 2008)